There are a bunch of reasons but the primary reason is that good ADCs are made using a different mixed signal process than microcontrollers. MCU ADCs are capacitive charge-balancing successive-approximation type which limits their sensitivity and precision.
Standalone ADCs also eliminate significant sources of noise like temperature fluctuations and electronic noise (the digital logic on the chip often runs at less than 1Mhz for example)
There are a bunch of reasons but the primary reason is that good ADCs are made using a different mixed signal process than microcontrollers. MCU ADCs are capacitive charge-balancing successive-approximation type which limits their sensitivity and precision.
Standalone ADCs also eliminate significant sources of noise like temperature fluctuations and electronic noise (the digital logic on the chip often runs at less than 1Mhz for example)